Brad Pitt and the woman with whom he was strolling through the streets of romantic Costiera Amalfi, Italy, on Oct. 30, looked like head-over-heels lovers, perhaps even newlyweds.

“There really seemed to be a chemistry between them,” said one onlooker. Unfortunately for Jennifer Aniston, she wasn’t the woman on her husband’s arm — it was Angelina Jolie. Star has never-before-seen photos showing the movie stars as they tenderly touched in the small, quaint seaside resort town near Naples.